In 1354/55 the Serbian Emperor Stefan Uroš IV Dušan (reigned 1331-1355) gave permission to his nobleman Vlatko Paskačić to donate the Church of Sveti Nikola in Psača, which Vlatko had erected on the inherited property (baština) of his father, together with the appertaining metochion to the Monastery of Hilandar (I vьspomenu carstvu mi prěvьzljubljenʼny i pravověrnii vlastelinь carstva mi Vladko ō crьkvy svetago Nikoly jaže jestь sьzdalь na svoōi baštině Pʼsači a sь blagoslovljenijemь carstva mi...i poljubi prěd carstvomʼ mi i priloži svoju baštinu crьkvь svetago Nikoli na Psači prěsvetěi Bogorodici hilandarьskoi sь vsěmь metehōmь). In the border description of Psača the rivers Moštanica and Lukavica and the topographical entity Golěm Ōdrьn are mentioned (Psačju sь vsěmi pravinami, a megja sela togo Moštanica kako pripada u rěku Lukavicu i do gde se izovrьša Moštanica i povrьhʼ planine nizʼ drumь kako spada posrěd golěmoga ōdrьna). Psača is registered as Starče, Psarče and Ipsarča in the Defter for the Sanjak Köstendil from the years 1570 to 1572.